1. Go to File > Share then click "Save To SkyDrive".

2. Sig-in using your Windows Live ID.
3. Once login, it will display all available folders, now select the folder where you would like to save the document.
3. Finally click the "Save As" button to upload the document. (It make take some time depending on your internet connection speed)
Save To SkyDrive feature is available in MS Word 2010, Excel 2010, and PowerPoint 2010.

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